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The effectiveness of a centralized Inspection/Maintenance (I/M) program, implemented in a major U.S. metropolitan area in 1991, is directly measured through ambient CO monitor data. A multi-factoral analysis is developed which quantifies effects due to the interaction of hourly traffic levels with wind vector and ambient temperature conditions, allowing a better measure of I/M effectiveness. The time-trend of the measured CO levels is seen to closely match those predicted by the analysis throughout the 7 year study period. An average ambient CO reduction of 1.3 ± 1.4 percent attributable to I/M is measured, with individual results of +1.5 percent, +5.8 percent, and -3.4 percent obtained for the three monitor locations studied.

This study examines the effect of a ceramic particle trap and a manganese fuel additive on the mutagenic activity and chemical composition of diesel exhaust particulate matter from a heavy-duty mining engine. Particles were collected by dilution tunnel sampling from a 4-cylinder, Caterpillar 3304, naturally-aspirated, indirect-injection engine operated at six steady-state conditions. Depending on engine load and speed the ceramic particle trap reduced the following emissions: particulate matter, 80 – 94%; soluble organic fraction (SOF), 83 – 95%; 1-nitropyrene, 94 – 96%; and SOF mutagencity, 72% (cycle-weighted average). When the Mn fuel additive was used without a ceramic particle trap the total cycle mutagenic activity emitted increased 7-fold, in part, due to elevated emissions of 1-nitropyrene.

Measurements of particle concentrations in one cylinder of a 1982 5.7 liter GM V-8 diesel engine have been made using a unique total cylinder sampling system. The first part of the paper is devoted to an examination of the performance of the sampling system. The role of blowoff and nucleation in the formation of sample artifacts is discussed. The remainder of the paper is devoted to the results of a study of the formation and removal of carbon particles during diesel engine combustion. Several operating conditions have been examined. The influence of injection timing, load, EGR, and oxygen addition on particle formation and removal has been investigated. The concentrations of volatile and nonvolatile particulate matter have been measured as a function of crankangle position. Particle formation begins 1-5 crankangle degrees (CAD) after the start of combustion.

In-cylinder and exhaust soot mass measurements have been made on a single-cylinder conversion of a 4-cylinder, 2.8 1, high-swirl, direct-injection diesel engine using a sampling system which allows dumping, diluting, quenching, and collecting the entire contents of the cylinder on a time scale o£ about 1 ms. Experiments have been performed at engine speeds of 1,000 and 1,500, and equivalence ratios, ϕ, of 0.4 and 0.7. Soot mass first appears shortly after top dead center and reaches a peak between 15 and 30 crankangle degrees after top dead center (CAD ATDC). After reaching its peak value, soot concentration decreases with increasing crankangle and approaches exhaust levels by 40-60 CAD ATDC. The time lag between the start of combustion and the first appearance of soot increases with ϕ and ranges from 0.2 to 1 ms. The initial rate of soot formation ranges from 0.26 to 0.30 mg ms−1 and varies little with speed or ϕ.

Experiments were performed to measure the number-weighted particle size distributions emitted from a gasoline direct injection (GDI) engine. Measurements were made on a late model vehicle equipped with a direct injection spark ignition engine. The vehicle was placed on a chassis dynamometer, which was used to load the engine to road load at five different vehicle speeds ranging from 15 - 100 km/hr. Dilution of the exhaust aerosol was carried out using a two-stage dilution system in which the first stage dilution occurs as a free jet. Particle size distributions were measured using a TSI 3934 scanning mobility particle sizer. Generally speaking, the presence of the additives did not have a strong, consistent influence on the particle emissions from this engine. The polyether amine demonstrated a reduction in particle number concentration as compared to unadditized base fuel.

This report describes tests of a fuel additive in a medium-duty, high-swirl, direct-injection diesel engine. The additive was found to have little influence on general combustion performance or on NOx emissions. On the other hand, it had a profound effect on particulate emissions. This was most clear under high load where particle emissions are highest. Here, when the engine was switched from running on the base fuel to the additive treated fuel, particle emissions at first increased and then fell to levels about 40% lower (by particle volume) than those initially produced by the base fuel. The additive had a long lasting effect. After running with the additive for about 25 hours, emission levels with the base fuel were only slightly higher than those with the additive treated fuel. We believe that the additive action is associated with a combination of cleaning and surface conditioning. More work should be done to understand the relative importance of these two mechanisms.

The formation of particles in the combustion chamber of a direct injection diesel engine has been studied with the use of the Total Cylinder Sampling Method. With this method, nearly the entire contents of the cylinder of an operating diesel engine can be quickly removed at various times during the combustion process. The particle mass and size distributions present in the sample can then be analyzed. If quenching of the combustion process is quick and complete, the resulting samples are representative of the particle mass and size distributions present in the cylinder near the time sampling begins. This paper discusses the effect of injection timing and piston bowl shape on the particle formation and oxidation. Example size distribution measurements are also shown. The particle concentrations in the cylinder were measured for three different injection timings with the standard piston installed in the engine.

Light absorption and scattering coefficients have been measured for particles emitted by two diesel engines; one direct injection and one indirect injection, operating over a range of speeds and loads. Integrating plate absorption measurements yield a specific absorption coefficient of 9.1 square meters per gram of non-volatile particulate matter at 550 nm wavelength. This absorption coefficient is inversely proportional to wavelength and independent of engine operating conditions or type. The scattering coefficient was simultaneously measured as 1.3 square meters per gram of undifferentiated particulate matter. These experimental results are shown to be in the range predicted by theoretical absorption and scattering calculations, which have been made for elongated carbon-void particles.

A unique system which allows sampling of the entire contents of one of the cylinders of a 5.7-liter V-8 indirect-injection diesel engine has been developed. An explosively actuated cutter ruptures a diaphragm in the combustion chamber and allows the contents of the cylinder to rush out and be subsequently diluted and quenched with cool nitrogen. Particles are collected with a high-volume impactor/filter system. This system has been used to collect a series of particle samples at crankangles ranging from 5 to 40 degrees after top dead center. Particle samples from the exhaust were also obtained. The samples have been extracted to determine the soluble organic fraction. These extracts have been analyzed for five polycyclic aromatic compounds: pyrene, fluoranthene, benz(a)pyrene, benz(k)fluoranthene, and 1-nitropyrene. The results indicate significant removal of the first four between the combustion chamber and the exhaust manifold.

A miniature homogenous charge compression ignition (HCCI) free-piston engine compressor aimed at an ankle-foot orthosis application is described. Analysis of the human ankle shows that a fluid power source in the neighborhood of 10 W is needed. To account for compressor and actuator inefficiencies, the power output at the engine cylinder is designed to be 30 W. A compact engine compressor package has been designed and mathematically modeled. Experiments using existing engine components characterized the leakage model. Through the dynamic simulation of the engine, major parameters of the engine have been specified. Simulations indicate that the HCCI free-piston engine compressor, designed in a prototype package scale of about 80×40×20 mm is a viable compact and efficient fluid power supply. Simulation results demonstrate that the overall efficiency of the engine compressor is expected to be 5.9% and that the package should have a higher energy density than batteries.

In this paper, a model-based linear estimator and a non-linear control law for an Fe-zeolite urea-selective catalytic reduction (SCR) catalyst for heavy duty diesel engine applications is presented. The novel aspect of this work is that the relevant species, NO, NO2 and NH3 are estimated and controlled independently. The ability to target NH3 slip is important not only to minimize urea consumption, but also to reduce this unregulated emission. Being able to discriminate between NO and NO2 is important for two reasons. First, recent Fe-zeolite catalyst studies suggest that NOx reduction is highly favored by the NO 2 based reactions. Second, NO2 is more toxic than NO to both the environment and human health. The estimator and control law are based on a 4-state model of the urea-SCR plant. A linearized version of the model is used for state estimation while the full nonlinear model is used for control design.

Although the urea-SCR technology exhibits high NO reduction efficiency over a wide range of temperatures among the lean NO reduction technologies, further improvement in low-temperature performance is required to meet the future emission standards and to lower the system cost. In order to improve the catalyst technologies and optimize the system performance, it is critical to understand the reaction mechanisms and catalyst behaviors with respect to operating conditions. Urea-SCR catalysts exhibit poor NO reduction performance at low-temperature operating conditions (T ≺ 150°C). We postulate that the poor performance is either due to NH₃ storage inhibition by species like hydrocarbons or due to competitive adsorption between NH₃ and other adsorbates such as H₂O and hydrocarbons in the exhaust stream. In this paper we attempt to develop one-dimensional models to characterize inhibition and competitive adsorption in Fe-zeolite-based urea-SCR catalysts based on bench reactor experiments.

The formation of NO2 in the cylinder of a diesel engine has been investigated using a total cylinder sampling technique and a simple kinetic model. Exhaust measurements of NO2 as a function of equivalence ratio and as function of time after engine start were made. Samples obtained by total cylinder sampling from an operating direct injection diesel engine showed NO2/NO ratios of 25 to 50%. This is much higher than the 1 to 3% which was measured in the exhaust. Simulations of the sampling process indicate that conversion of NO to NO2 is at least partially responsible for the high NO2/NO measurements. However, the processes which produce the NO to NO2 conversion during the sampling also occur during normal combustion. This may lead to high NO2 concentrations during the combustion cycle which are then lowered during the expansion to the measured exhaust concentrations.

Nanoparticle formation during exhaust sampling and dilution has been examined using a two-stage micro-dilution system to sample the exhaust from a modern, medium-duty diesel engine. Growth rates of nanoparticles at different exhaust dilution ratios and temperatures have been determined by monitoring the evolution of particle size distributions in the first stage of the dilution system. Two methods, graphical and analytical, are described to determine particle growth rate. Extrapolation of size distribution down to 1 nm in diameter has been demonstrated using the graphical method. The average growth rate of nanoparticles is calculated using the analytical method. The growth rate ranges from 6 nm/sec to 24 nm/sec, except at a dilution ratio of 40 and primary dilution temperature of 48 °C where the growth rate drops to 2 nm /sec. This condition seems to represent a threshold for growth. Observed nucleation and growth patterns are consistent with predictions of a simple physical model.

Vibration signals from diesel engines were analyzed for the purpose of isolating signals relating to injection or combustion which could be used to time the engines. Nonintrusive sensors, magnetically attached to the engine, were used to obtain these vibration signals. Components believed to be associated with combustion or fuel injection were electronically isolated from the remaining engine noise, and subsequently processed to produce specific timing signals. Digital data acquisition and averaging methods were used, coupled with computerized frequency analysis. The signals were experimentally correlated with the combustion process over a wide range of injection timing. The electronic processing system developed provides a real time digital measure of the timing. Data on the accuracy and correlation of experimental measurements will be presented.

Four-way, integrated, diesel emission control systems that combine selective catalytic reduction for NOx control with a continuously regenerating trap to remove diesel particulate matter were evaluated under real-world, on-road conditions. Tests were conducted using a semi-tractor with an emissions year 2000, 6-cylinder, 12 L, Volvo engine rated at 287 kW at 1800 rpm and 1964 N-m. The emission control system was certified for retrofit application on-highway trucks, model years 1994 through 2002, with 4-stroke, 186-373 kW (250-500 hp) heavy-duty diesel engines without exhaust gas recirculation. The evaluations were unique because the mobile laboratory platform enabled evaluation under real-world exhaust plume dilution conditions as opposed to laboratory dilution conditions. Real-time plume measurements for NOx, particle number concentration and size distribution were made and emission control performance was evaluated on-road.

In this paper, we develop a method for optimizing urea dosing to minimize the downstream readings from a production NOx sensor that has cross-sensitivity to ammonia. This approach favors high NOx conversion and reduced ammonia slip. The motivation for this work is to define a process to identify the maximum selective catalytic reduction SCR performance bounds for a given drive cycle. The approach uses a model structure that has a closed-form optimal solution for the urea injection. Every aftertreatment system has its own, unique model, which must be identified and validated. To demonstrate the approach, a model is identified and validated using experimental SCR input/output NOx sensor data from a 2010 Cummins 6.7L ISB production engine. The optimal control law is then simulated and its performance compared against the simulated performance of the SCR using experimental data for its inlet conditions.

This paper describes an examination of the origin of the response of a real-time exhaust particle sensor. The sensor works by detecting the net electrical charge carried by diesel exhaust particles emitted during exhaust blow-down. The distribution of charge on these particles has been measured using an electrical mobility analysis system. The results show that the exhaust particles are highly charged and that their charge distributions are nearly symmetrical. The sensor signal results from a slight departure from this symmetry. The results suggest that most of the charge on the exhaust particles results from bipolar charging by flame ions during combustion, but that the net charge detected by the sensor results from surface interactions which some of the larger particles undergo during exhaust blowdown.

Carbon black particles, which morphologically and chemically simulate a diesel exhaust soot, were mixed with the intake air of a single-cylinder direct injection diesel engine to investigate the efficiency of their removal by oxidation in the combustion chamber. An aerosol generation system, which is capable of generating carbon black aerosol of a size distribution and mass flow rate comparable to those of the soot agglomerates, was developed first. The aerosol was then introduced into the engine which was operating on conventional fuel. Four methods were used to characterize the exhaust particles: an electrical aerosol analyzer, a condensation nuclei counter, a low volume filter, and a micro-orifice cascade impactor. The size distribution and concentration of the diesel soot particles in the lubricants were investigated by methods of photosedimentation and quantitative spectrophotometry, respectively.

Time resolved primary and agglomerate particle size distribution measurements have been made on samples obtained from within the cylinder and from the exhaust of a single-cylinder modification of a 2.8 liter displacement, four-cylinder, naturally-aspirated, high swirl, direct-injection diesel engine. The total cylinder sampling method has been used to sample, quench, and dilute the entire contents of the cylinder in about 1 ms. Experiments have been performed at an equivalence ratio of 0.7 and a speed of 1000 RPM. An electrostatic aerosol sampler and a transmission electron microscope have been used to determine primary and agglomerate particle size distributions for both in-cylinder and exhaust samples. An electrical aerosol analyzer and a diffusion battery followed by a condensation nucleus counter were used to further characterize the agglomerate size distributions of exhaust samples.